孙晓甫 研究员 孙晓甫 研究员

最小化 最大化

孙晓甫 研究员

邮箱：sunxiaofu@iccas.ac.cn

个人简介

孙晓甫，中国科学院化学研究所研究员。2011 年在南开大学化学学院获得学士学位；2014 年在中国人民大学化学系获得硕士学位；2017 年在中国科学院化学研究所获得博士学位；同年赴新加坡南洋理工大学做博士后研究。2019年12 月至今任中国科学院化学研究所研究员，博士生导师。主要开展惰性化学键活化转化、可再生碳资源转化利用方面研究，如电化学转化CO2合成高附加值化学品。至今在J. Am. Chem. Soc., Angew. Chem. Int. Ed., Nat. Commun., Adv. Mater.等期刊发表SCI 论文100 余篇。获首届IUPAC-NHU国际绿色化学进步奖，中国科学院杰出科技成就奖（绿色化学集体）等。

教育背景

2014-09至2017-07，中国科学院化学研究所，博士

2011-09至2014-07，中国人民大学，理学院化学系，硕士

2007-09至2011-07，南开大学，化学学院，学士

工作经历

2019-12至今，中国科学院化学研究所，中国科学院胶体、界面与化学热力学重点实验室，研究员

2017-10至2019-10，新加坡南洋理工大学，材料科学与工程学院，博士后

发表论文

(# Equally Contributing Authors，* Corresponding Authors)

  1. Jia, S.; Sun, X.*; Han, B.*, Electrocatalytic systems for NOx upgrading, Chem. Commun. 2025, DOI: 10.1039/D4CC05762G.
  2. Feng, J.; Wu, L.; Song, X.; Zhang, L.; Jia, S.; Ma, X.; Tan, X.; Kang, X.; Zhu, Q.; Sun, X.*; Han, B.*, CO2 electrolysis to multi-carbon products in strong acid at ampere-current levels on La-Cu spheres with channels, Nat. Commun. 2024, 15, 4821.
  3. Zhang, L.; Feng, J.; Wang, R.; Wu, L.; Song, X.; Jin, X.; Tan, X.; Jia, S.; Ma, X.; Jing, L.; Zhu, Q.; Kang, X.; Zhang, J.; Sun, X.*; Han, B.*, Switching CO-to-Acetate Electroreduction on Cu Atomic Ensembles, J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.4c13197.
  4. Jia, S.; Zhang, L.; Liu, H.; Wang, R.; Jin, X.; Wu, L.; Song, X.; Tan, X.; Ma, X.; Feng, J.; Zhu, Q.; Kang, X.; Qian, Q.; Sun, X.*; Han, B.*, Upgrading of nitrate to hydrazine through cascading electrocatalytic ammonia production with controllable N-N coupling, Nat. Commun. 2024, 15, 8567.
  5. Jia, S.; Wu, L.; Tan, X.; Feng, J.; Ma, X.; Zhang, L.; Song, X.; Xu, L.; Zhu, Q.; Kang, X.; Sun, X.*; Han, B.*, Synthesis of Hydroxylamine via Ketone-Mediated Nitrate Electroreduction, J. Am. Chem. Soc. 2024, 146, 10934-10942.
  6. Jia, S.; Wang, R.; Jin, X.; Liu, H.; Wu, L.; Song, X.; Zhang, L.; Ma, X.; Tan, X.; Sun, X.*; Han, B.*, In situ Generation of Cyclohexanone Drives Electrocatalytic Upgrading of Phenol to Nylon-6 Precursor, Angew. Chem. Int. Ed. 2024, 63, e202410972.
  7. Jia, S.; Wu, L.; Liu, H.; Wang, R.; Sun, X.*; Han, B.*, Nitrogenous Intermediates in NOx-involved Electrocatalytic Reactions, Angew. Chem. Int. Ed. 2024, 63, e202400033.
  8. Song, X.; Ma, X.; Chen, T.; Xu, L.; Feng, J.; Wu, L.; Jia, S.; Zhang, L.; Tan, X.; Wang, R.; Chen, C.; Ma, J.; Zhu, Q.; Kang, X.; Sun, X.*; Han, B.*, Urea Synthesis via Coelectrolysis of CO2 and Nitrate over Heterostructured Cu-Bi Catalysts, J. Am. Chem. Soc. 2024, 146, 25813-25823.
  9. Guo, W.; Tan, X.; Jia, S.; Liu, S.; Song, X.; Ma, X.; Wu, L.; Zheng, L.; Sun, X.*; Han, B.*, Asymmetric Cu sites for enhanced CO2 electroreduction to C2+ products. CCS Chem. 2024, 6, 1231-1239.
  10. Zhang, L.; Sun, X.*; Han, B.*, Electrocatalytic CO2 reduction to a single multi-carbon product. Sci. Bull. 2024, 69, 563-565.
  11. Liu, H.; Jia, S.; Wu, L.; He, L.*; Sun, X.*; Han, B.*; Active Hydrogen-Controlled CO2/N2/NOx Electroreduction: From Mechanism Understanding to Catalyst Design. Innov. Mater. 2024, 2, 100058.
  12. Wu, L.; Jia, S.; Zhang, L.; Wang, R.; Feng, J.; Sun, X.*; Han, B.*, Efficient nitrate electroreduction over Mn-doped Cu catalyst via regulating N-containing intermediates adsorption configuration. Sci. China Chem. 2024, 67, 1969-1975.
  13. Dong, X.; Sun, X.*; Jia, S.; Han, S.; Zhou, D.; Yao, T.; Wang, M.; Fang, M.; Wu, H.*; Han, B.*; Electrochemical CO2 Reduction to C2+ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts, Acta Phys. -Chim. Sin. 2024, 40, 2404012.
  14. Sui, X.; Wu, L.; Jia, S.; Jin, X.; Sun, X.*; Han, B.*; CO2/NOx-involved Electrochemical C-N Coupling Reactions, Chem. Res. Chin. Univ. 2024, 40, 764-775.
  15. Zhan, X.; Zhang, L.; Choi, J.; Tan, X.*; Hong, S.; Wu, T.-S.; Xiong, P.; Soo, Y.-L.; Hao, L.; Li, M. M.-J.; Xu, L.; Robertson, A. W.; Jung, Y.*; Sun, X.*; Sun, Z.*; A Universal Synthesis of Single-Atom Catalysts via Operando Bond Formation Driven by Electricity, Adv. Sci. 2024, 11, 2401814.
  16. Zhang, L.; Feng, J.; Liu, S.; Tan, X.; Wu, L.; Jia, S.; Xu, L.; Ma, X.; Song, X.; Ma, J.; Sun, X.*; Han, B.*, Atomically Dispersed Ni-Cu Catalysts for pH-Universal CO2 Electroreduction. Adv. Mater. 2023, 29, 2209590.
  17. Feng, J.; Wu, L.; Liu, S.; Xu, L.; Song, X.; Zhang, L.; Zhu, Q.; Kang, X.; Sun, X.*; Han, B.*, Improving CO2-to-C2+ Product Electroreduction Efficiency via Atomic Lanthanide Dopant-Induced Tensile-Strained CuOx Catalysts. J. Am. Chem. Soc. 2023, 145, 9857-9866.
  18. Feng, J.; Zhang, L.; Liu, S.; Xu, L.; Ma, X.; Tan, X.; Wu, L.; Qian, Q.; Wu, T.; Zhang, J.; Sun, X.*; Han, B.*, Modulating adsorbed hydrogen drives electrochemical CO2-to-C2 products. Nat. Commun. 2023, 14, 4615.
  19. Wu, L.; Feng, J.; Zhang, L.; Jia, S.; Song, X.; Zhu, Q.; Kang, X.; Xing, X.; Sun, X.*; Han, B.*, Boosting Electrocatalytic Nitrate-to-Ammonia via Tuning of N-Intermediate Adsorption on a Zn-Cu Catalyst. Angew. Chem. Int. Ed. 2023, 62, e202307952.
  20. Zhang, L.; Feng, J.; Wu, L.; Ma, X.; Song, X.; Jia, S.; Tan, X.; Jin, X.; Zhu, Q.; Kang, X.; Ma, J.; Qian, Q.; Zheng, L.; Sun, X.*; Han, B.*, Oxophilicity-Controlled CO2 Electroreduction to C2+ Alcohols over Lewis Acid Metal-Doped Cuδ+ Catalysts. J. Am. Chem. Soc. 2023, 145, 21945-21954.
  21. Xu, L.; Feng, J.; Wu, L.; Song, X.; Tan, X.; Zhang, L.; Ma, X.; Jia, S.; Du, J.; Chen, A.; Sun, X.*; Han, B.*, Identifying the Optimal Oxidation State of Cu for Electrocatalytic CO2-to-C2+ Products. Green Chem. 2023, 25, 1326-1331.
  22. Wu, L.; Zhang, L.; Liu, S.; Feng, J.; Xu, L.; Tan, X.; Ma, X.; Sun, X.*, Promoting ambient ammonia electrosynthesis on modulated Cuδ+ catalysts by B-doping. J. Mater. Chem. A 2023, 11, 5520-5526.
  23. Song, X.; Xu, L.; Sun, X.*; Han, B.*, In situ/operando characterization techniques for electrochemical CO2 reduction. Sci. China Chem. 2023, 66, 315-323.
  24. Zhang, L.; Sun, X.*, Electrocatalytic reduction of CO2 captured in the carbonate form to C2+ products. Chinses Sci. Bull. 2023, 68, 2852-2854.
  25. Tan, X.; Jia, S.; Song, X.; Ma, X.; Feng, J.; Zhang, L.; Wu, L.; Du, J.; Chen, A.; Zhu, Q.; Sun, X.*; Han, B.*, Zn-Induced Electron-Rich Sn Catalysts Enable Highly Efficient CO2 Electroreduction to Formate. Chem. Sci. 2023, 14, 8214-8221.
  26. Ma, X.; Song, X.; Zhang, L.; Wu, L.; Feng, J.; Jia, S.; Tan, X.; Xu, L.; Sun, X.*; Han, B.*, Stabilizing Cu0-Cu+ sites by Pb-doping for highly efficient CO2 electroreduction to C2 products. Green Chem. 2023,25, 7635-7641.
  27. Jia, S.; Tan, X.; Wu, L.; Ma, X.; Zhang, L.; Feng, J.; Xu, L.; Song, X.; Zhu, Q.; Kang, X.; Sun, X.*; Han, B.*, Integration of plasma and electrocatalysis to synthesize cyclohexanone oxime under ambient conditions using air as a nitrogen source. Chem. Sci. 2023, 14, 13198-13204.
  28. Jia, S.; Tan, X.; Wu, L.; Zhao, Z.; Song, X.; Feng, J.; Zhang, L.; Ma, X.; Zhang, Z.; Sun, X.*; Han, B.*, Lignin-derived carbon nanosheets boost electrochemical reductive amination of pyruvate to alanine. iScience 2023, 26, 107776.
  29. Jia, S.; Tan, X.; Wu, L.; Feng, J.; Zhang, L.; Xu, L.; Wang, R.; Sun, X.*; Han, B.*, Defective PrOx for Efficient Electrochemical NO2–-to-NH3 in a Wide Potential Range. Chemistry 2023, 5, 753-761.
  30. Jia, S.; Wu, L.; Xu, L.; Sun, X.*; Han, B.*, Multicomponent Catalyst Design for CO2/N2/NOx Electroreduction. Ind. Chem. Mater. 2023, 1, 93-105.
  31. Xu, L.; Ma, X.; Wu, L.; Tan, X.; Song, X.; Zhu, Q.; Chen, C.; Qian, Q.; Liu, Z.; Sun, X.*; Liu, S.*; Han, B.*, In Situ Periodic Regeneration of Catalyst during CO2 Electroreduction to C2+ Products. Angew. Chem. Int. Ed. 2022, 61, e202210375.
  32. Tan, X.; Guo, W.; Liu, S.; Jia, S.; Xu, L.; Feng, J.; Yan, X.; Chen, C.; Zhu, Q.; Sun, X.*; Han, B.*, A Sn-stabilized Cuδ+ electrocatalyst toward highly selective CO2-to-CO in a wide potential range. Chem. Sci. 2022, 13, 11918-11925.
  33. Ma, X.; Xu, L.; Liu, S.; Zhang, L.; Tan, X.; Wu, L.; Feng, J.; Liu, Z.; Sun, X.*; Han, B.*, Electrochemical C-C Coupling between CO2 and formaldehyde in to ethanol. Chem Catal. 2022, 2, 3207-3224.
  34. Song, X.; Guo, W.; Ma, X.; Xu, L.; Tan, X.; Wu, L.; Jia, S.; Wu, T.; Ma, J.; Zhang, F.; Jia, J.; Sun, X.*; Han, B.*, Boosting CO2 electroreduction over Co nanoparticles supported on N,B-co-doped graphitic carbon. Green Chem. 2022, 24, 1488-1493.
  35. Wan, X.; Guo, W.; Dong, X.; Wu, H.; Sun, X.*; Chu, M.; Han, S.; Zhai, J.; Xia, W.; Jia, S.; He, M.; Han, B.*, Boosting nitrate electroreduction to ammonia on NbOx via constructing oxygen vacancies. Green Chem. 2022, 24, 1090-1095.
  36. Tan, X.; Sun, X.*; Han, B.*, Ionic liquid-based electrolytes for CO2 electroreduction and CO2 electroorganic transformation. Natl. Sci. Rev. 2022, 9, nwab022.
  37. Jia, S.; Ma, X.; Sun, X.*; Han, B.*, Electrochemical Transformation of CO2 to Value-Added Chemicals and Fuels. CCS Chem. 2022, 4, 3213-3229.
  38. Song, X.#; Jia, S.#; Xu, L.; Feng, J.; He, L.; Sun, X.*; Han, B.*, Towards sustainable CO2 electrochemical transformation via coupling design strategy. Mater. Today Sustain. 2022, 19, 100179.
  39. Wang, R.; Jia, S.; Wu, L.; Sun, X.*; Han, B.*, CO2-involved Electrochemical C-N Coupling into Value-Added Chemicals. Chem. J. Chinese U. 2022, 43, 20220395.
  40. Jin, X.; Zhang, L.; Sun, X.*; Han, B.*, Electrocatalytic CO2 Reduction over Single-Atom Catalysts. Chem. J. Chinese U. 2022, 43, 20220035.
  41. Guo, W.; Tan, X.; Bi, J.; Xu, L.; Yang, D.; Chen, C.; Zhu, Q.; Ma, J.; Tayal, A.; Ma, J.; Huang, Y.; Sun, X.*; Liu, S.*; Han, B.*, Atomic Indium Catalysts for Switching CO2 Electroreduction Products from Formate to CO. J. Am. Chem. Soc. 2021, 143, 6877-6885.
  42. Guo, W.; Liu, S.; Tan, X.; Wu, R.; Yan, X., Chen, C.; Zhu, Q.; Zheng, L.; Ma, J.; Zhang, J.; Huang, Y.; Sun, X.*; Han, B.*, Highly Efficient CO2 Electroreduction to Methanol through Atomically Dispersed Sn Coupled with Defective CuO Catalysts. Angew. Chem. Int. Ed. 2021, 60, 21979-21987.
  43. Chen, C.; Yan, X.; Wu, R.; Wu, Y.; Zhu, Q.; Hou, M.; Zhang, Z.; Fan, H.; Ma, J.; Huang, Y.; Ma, J.; Sun, X.*; Lin, L.*; Liu, S.*; Han, B.*, Quasi-square-shaped cadmium hydroxide nanocatalysts for electrochemical CO2 reduction with high efficiency. Chem. Sci. 2021, 12, 11914-11920.
  44. Wu, L.; Guo, W.; Sun, X.*; Han, B.*, Rational design of nanocatalysts for ambient ammonia electrosynthesis. Pure Appl. Chem. 2021, 93, 777-797.
  45. Chen, C.; Sun, X.*; Yan, X.; Wu, Y.; Liu, H.; Zhu, Q.; Bediako, B. B. A.; Han, B.*, Boosting CO2 Electroreduction on N,P-Co-Doped Carbon Aerogels. Angew. Chem. Int. Ed. 2020, 59, 11123-11129.
  46. Guo, W.; Bi, J.; Zhu, Q.; Ma, J.; Yang, G.; Wu, H.; Sun, X.*; Han, B.*, Highly Selective CO2 Electroreduction to CO on Cu-Co Bimetallic Catalysts. ACS Sustainable Chem. Eng. 2020, 8, 12561-12567.
  47. Lu, L.; Guo, W.; Chen, C.; Zhu, Q.; Ma, J.; Wu, H.; Yang, D.; Yang, G.; Sun, X.*; Han, B.*, Synthesis of Sn4P3/reduced graphene oxide nanocomposites as highly efficient electrocatalysts for CO2 reduction. Green Chem. 2020, 22, 6804-6808.
  48. Chen, C.; Sun, X.*; Yan, X.; Wu, Y.; Liu, M.; Liu, S.; Zhao, Z.; Han, B.*, A strategy to control the grain boundary density and Cu+/Cu0 ratio of Cu-based catalysts for efficient electroreduction of CO2 to C2 products. Green Chem. 2020, 22, 1572-1576.
  49. Sun, X.; Chen, C.; Liu, S.; Hong, S.; Zhu, Q.; Qian, Q.; Han, B.*; Zhang, J.; Zheng, L., Aqueous CO2 Reduction with High Efficiency Using α-Co(OH)2-Supported Atomic Ir Electrocatalysts. Angew. Chem. Int. Ed. 2019, 58, 4669-4673.
  50. Chen, C.; Sun, X.*; Yang, D.; Lu, L.; Wu, H.; Zheng, L.; An, P.; Zhang, J.; Han, B.*, Enhanced CO2 electroreduction via interaction of dangling S bonds and Co sites in cobalt phthalocyanine/ZnIn2S4 hybrids. Chem. Sci. 2019, 10, 1659-1663.
  51. Guo, W.; Sun, X.*; Chen, C.; Yang, D.; Lu, L.; Yang, Y.; Han, B.*, Metal-organic framework-derived indium-copper bimetallic oxide catalysts for selective aqueous electroreduction of CO2. Green Chem. 2019, 21, 503-508.
  52. Lu, L.; Sun, X.*; Ma, J.; Yang, D.; Wu, H.; Zhang, B.; Zhang, J.; Han, B.*, Highly Efficient Electroreduction of CO2 to Methanol on Palladium-Copper Bimetallic Aerogels. Angew. Chem. Int. Ed. 2018, 57, 14149-14153.
  53. Chen, C.; Sun, X.*; Lu, L.; Yang, D.; Ma, J.; Zhu, Q.; Qian, Q.; Han, B.*, Efficient Efficient electroreduction of CO2 to C2 products over B-doped oxide-derived copper. Green Chem. 2018, 20, 4579-4583.
  54. Lu, L.; Sun, X.*; Ma, J.; Zhu, Q.; Wu, C.; Yang, D.; Han, B.*, Selective Selective electroreduction of carbon dioxide to formic acid on electrodeposited SnO2@N-doped porous carbon catalysts. Sci. China Chem. 2018, 61, 228-235.
  55. Sun, X.; Lu, L.; Zhu, Q.; Wu, C.; Yang, D.; Chen, C.; Han, B.*, MoP Nanoparticles Supported on Indium-Doped Porous Carbon: Outstanding Catalysts for Highly Efficient CO2 Electroreduction. Angew. Chem. Int. Ed. 2018, 57, 2427-2431.
  56. Tao, H.#; Sun, X.#; Back, S.; Han, Z.; Zhu, Q.; Robertson, A. W.; Ma, T.; Fan, Q.; Han, B.*; Jung, Y.*; Sun, Z.*, Doping palladium with tellurium for the highly selective electrocatalytic reduction of aqueous CO2 to CO. Chem. Sci. 2018, 9, 483-487.
  57. Sun, X.; Zhu, Q.; Hu, J.; Kang, X.; Ma, J.; Liu, Z.; Han, B.*, N,N-Dimethylation of nitrobenzenes with CO2 and water by electrocatalysis. Chem. Sci. 2017, 8, 5669-5674.
  58. Sun, X.; Zhu, Q.; Kang, X.; Liu, H.; Qian, Q.; Ma, J.; Zhang, Z.; Yang, G.; Han, B.*, Design of a Cu(i)/C-doped boron nitride electrocatalyst for efficient conversion of CO2 into acetic acid. Green Chem. 2017, 19, 2086-2091.
  59. Sun, X.; Zhu, Q.; Kang, X.; Liu, H.; Qian, Q.; Zhang, Z.; Han, B.*, Molybdenum-Bismuth Bimetallic Chalcogenide Nanosheets for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Methanol. Angew. Chem. Int. Ed. 2016, 55, 6771-6775.
  60. Sun, X.; Kang, X.; Zhu, Q.*; Ma, J.; Yang, G.; Liu, Z.; Han, B.*, Very highly efficient reduction of CO2 to CH4 using metal-free N-doped carbon electrodes. Chem. Sci. 2016, 7, 2883-2887.
  61. Sun, X.; Liu, Z.; Xue, Z.; Zhang, Y.; Mu, T.*, Extraction of 5-HMF from the conversion of glucose in ionic liquid [Bmim]Cl by compressed carbon dioxide. Green Chem. 2015, 17, 2719-2722.
  62. Sun, X.; Huang, C.; Xue, Z.; Mu, T.*, An Environmentally Benign Cycle To Regenerate Chitosan and Capture Carbon Dioxide by Ionic Liquids. Energy Fuels 2015, 29, 1923-1930.
  63. Sun, X.; Huang, C.; Xue, Z.; Yan, C.; Mu, T.*, Efficient and Sustainable Strategy for the Hierarchical Separation of Lignin-Based Compounds Using Ionic Liquid/Compressed CO2. Energy Fuels 2015, 29, 2564-2570.
  64. Sun, X.; Chi, Y.; Mu, T.*, Studies on staged precipitation of cellulose from an ionic liquid by compressed carbon dioxide. Green Chem. 2014, 16, 2736-2744.
  65. Sun, X.; Xue, Z.; Mu, T.*, Precipitation of chitosan from ionic liquid solution by the compressed CO2 anti-solvent method. Green Chem. 2014, 16, 2102-2106.
  66. Sun, X.; Liu, S.; Khan, A.; Zhao, C.; Yan, C.; Mu, T.*, Ionicity of acetate-based protic ionic liquids: evidence for both liquid and gaseous phases. New J. Chem. 2014, 38, 3449-3456.
  67. Sun, X.; Tian, Q.; Xue, Z.; Zhang, Y.; Mu, T.*, The dissolution behaviour of chitosan in acetate-based ionic liquids and their interactions: from experimental evidence to density functional theory analysis. RSC Adv. 2014, 4, 30282-30291.